How can i add tow property in my model in EF code first from one model?

I suppose your model is more complicated than just FromCity and ToCity because I don't think it's a good idea to store such information in a different table. Yet, You can use inheritance in this case.

The table-per-hierarchy (TPH) pattern is used by default to map the inheritance in EF. TPH stores the data for all types in the hierarchy in a single table.

However, for your scenario, you can have a base class that holds all related attributes.

public class CityBase
{
    public int Id { get; set; }
    public string Name { get; set; } = string.Empty;
}

Then suppose you need two entities as per your scenario:

public class FromCity : CityBase
{
    public virtual ICollection<Order> Orders { get; set; } = null!;
}
public class ToCity : CityBase
{
    public virtual ICollection<Order> Orders { get; set; } = null!;
}

And the order entity:

public class Order
{
    public int Id { get; set; }
    public string OrderTitle { get; set; } = string.Empty;
    public virtual FromCity FromCity { get; set; } = null!;
    public virtual ToCity ToCity { get; set; } = null!;
}

This approach can solve your problem with a One-to-Many relationship between Orders and FromCity, ToCity as per below diagram: